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Synlett 2001; 2001(8): 1249-1250
DOI: 10.1055/s-2001-16041
DOI: 10.1055/s-2001-16041
letter
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Short and Stereoselective Total Synthesis of (±)-Dihydrosesamin and (±)-Acuminatin Methyl Ether by Radical Cyclisation of Epoxides Using a Transition-Metal Radical Source
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Publication History
Publication Date:
31 December 2001 (online)
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Short, efficient and stereoselective synthesis of a furano lignans, (±)-Dihydrosesamin and (±)-Acuminatin Methyl Ether has been achieved in good overall yield through the radical cyclisation of epoxides using a Ti(III) reagent as the radical initiator.
stereoselective - radical cyclisation - epoxide - transition-metal