A Convenient Synthesis of Alkyl- and Dialkylphenanthren-9-ylamines

Christophe Hoarau; Axel Couture; Eric Deniau; Pierre Grandclaudon

doi:10.1055/s-2001-16090

PAPER

A Convenient Synthesis of Alkyl- and Dialkylphenanthren-9-ylamines

Christophe Hoarau, Axel Couture*, Eric Deniau, Pierre Grandclaudon
Laboratoire de Chimie Organique Physique, ESA CNRS N° 8009, Université des Sciences et Technologies de Lille, 59655 Villeneuve d’Ascq Cédex, France
Fax: +33(3)20336309; e-Mail: Axel.Couture@univ-lille1.fr;

Abstract

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Abstract

A variety of alkyl- and dialkylphenanthren-9-ylamines 1 and 2 have been prepared by radical-mediated cyclizations of the corresponding diaryleneamines 3 issued from Horner reactions between appropriate phosphorylated dibenzylamines 4 and halogenoarylaldehydes 5.

Key words

aminophenanthrenes - carbanions - Horner reactions - radical reactions - cyclizations

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References

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