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Synlett 2001; 2001(9): 1479-1481
DOI: 10.1055/s-2001-16779
DOI: 10.1055/s-2001-16779
letter
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Diastereoselective Titanocene-Catalyzed Oxidative Cyclization of Bishomoallylic Alcohols
Further Information
Publication History
Publication Date:
28 August 2001 (online)
Bishomoallylic alcohols are converted in good yields and diastereoselectivity into tetrahydrofuranols and tetrahydropyranols by Cp2TiCl2/t-butyl hydroperoxide/activated 4 Å molecular sieves system.
epoxidation - cyclization - metallocenes - tetrahydrofuranols - tetrahydropyranols