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Synlett 2001; 2001(10): 1571-1572
DOI: 10.1055/s-2001-17484
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Polymer-Supported Selenol Esters as Useful Acylating Reagents. Application to α,β-Acetylenic Ketones Synthesis

Hao Qian* , Li-Xiong Shao, Xian Huang
  • *Department of Chemistry, Zhejiang University, Xi-xi Campus, Hangzhou 310028, P. R. China; Fax + 86(571)88 80 70 77; E-mail: huangx@mail.hz.zj.cn
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Publication Date:
27 September 2001 (online)

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Three novel polystyrene supported selenol esters were synthesized and used as acyl transfer agents to prepare α,β-acetylenic ketones by reaction with alkynylcoppers.

solid-phase synthesis - selenol ester - acyl transfer agent - alkynylcopper - acetylenic ketone