Tetrabutylammonium Peroxydisulfate in Organic Synthesis; XI. A Novel and Selective Approach to the Oxidative Deprotection of Allyl Ethers with Tetrabutylammonium Peroxydisulfate

Fen-Er Chen; Xiou-Hong Ling; Yan-Ping He; Xiao-Hua Peng

doi:10.1055/s-2001-17515

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Synthesis 2001(12): 1772-1774
DOI: 10.1055/s-2001-17515

SHORTPAPER

Tetrabutylammonium Peroxydisulfate in Organic Synthesis; XI. [1] A Novel and Selective Approach to the Oxidative Deprotection of Allyl Ethers with Tetrabutylammonium Peroxydisulfate

Fen-Er Chen*, Xiou-Hong Ling, Yan-Ping He, Xiao-Hua Peng
Department of Chemistry, Fudan University, Shanghai 200433, People’s Republic of China
Fax: +86(21)65642021; e-Mail: rfchen@fudan.edu.cn;

Further Information

Publication History

Received 7 May 2001
Publication Date:
11 August 2004 (online)

Abstract
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Abstract

A tetrabutylammonium peroxydisulfate-mediated oxidative procedure for the mild selective deprotection of allyl ethers to form the corresponding alcohols is described. The alcohols are obtained in yields of 81-85% and the method is compatible with several functional groups under these reaction conditions.

Key words

tetrabutylammonium peroxydisulfate - allyl ethers - protecting group - deprotection

References

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