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Synlett 2001; 2001(11): 1784-1786
DOI: 10.1055/s-2001-18077
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Preparation of Tricyclic and Tetracyclic Benzoxepin Derivatives by One-Pot Enyne Metathesis/Diels-Alder Reaction

Marcial Moreno-Mañas* , Roser Pleixats, Antoni Santamaria
  • *Department of Chemistry, Universitat Autònoma de Barcelona, Cerdanyola, 08193-Barcelona, Spain; Fax + 34(93)5 81 12 65; E-mail: Roser.Pleixats@uab.es
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Publication History

Publication Date:
29 October 2001 (online)

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Tricyclic and tetracyclic benzoxepin derivatives were prepared by one-pot enyne metathesis/Diels-Alder reactions starting from differently substituted 2-allyl-1-propargyloxybenzenes (endo stereoselectivity).

ruthenium - catalysis - enyne metathesis - Diels-Alder reactions - tandem reactions