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Synlett 2001; 2001(1): 0096-0098
DOI: 10.1055/s-2001-9704
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Primary Geminal Bishydroperoxides by Hydroperoxide Rearrangement

Hans-Jürgen Hamann* , Jürgen Liebscher
  • *Institut für Chemie, Humboldt-Universität Berlin, Hessische Str. 1-2, 10115 Berlin, Germany; Fax +49(30)20 93 89 07; E-mail: liebscher@chemie.hu-berlin.de
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Publication Date:
31 December 2001 (online)

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Novel primary geminal bishydroperoxides 6 were synthesized by acid catalyzed reaction of bicyclic alcohols 1 with hydrogen peroxide via rearrangement of intermediate bicyclic hydroperoxides 2.

hydroperoxides - rearrangement - geminal bishydroperoxides - phenols