Synthesis of β-Functionalized α,β-Unsaturated Oximes via Silylation of Nitro Compounds

Vitaly M. Danilenko; Alexander A. Tishkov; Sema L. Ioffe; Ilya M. Lyapkalo; Yury A. Strelenko; Vladimir A. Tartakovsky

doi:10.1055/s-2002-23539

PAPER

Synthesis of β-Functionalized α,β-Unsaturated Oximes via Silylation of Nitro Compounds [1]

Vitaly M. Danilenko^a, Alexander A. Tishkov*^b, Sema L. Ioffe*^b, Ilya M. Lyapkalo^a, Yury A. Strelenko^b, Vladimir A. Tartakovsky^b
^a Moscow Chemical Lyceum, 4 Tamozheny proezd,109033, Moscow, Russian Federation
Fax: +7(095)3623440; e-Mail: dan@1303.ru;
^b N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation
Fax: +7(095)1355328; e-Mail: tishkov@cacr.ioc.ac.ru;

Abstract

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Abstract

A general method for the synthesis of conjugated enoximes 2 via silylation of functionalized aliphatic nitro compounds 1 has been elaborated. The configuration of obtained products has been determined by NMR spectroscopy.

Key words

nitro compounds - elimination - stereoselectivity - silylation - conjugated enoximes

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References

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