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Synlett 2002(5): 0707-0710
DOI: 10.1055/s-2002-25352
DOI: 10.1055/s-2002-25352
LETTER
© Georg Thieme Verlag Stuttgart · New York
Juliá-Colonna Asymmetric Epoxidation in a Continuously Operated Chemzyme Membrane Reactor
Further Information
Publication History
Received
4 February 2002
Publication Date:
07 February 2007 (online)


Abstract
Two novel soluble polymer-bound oligo-l-leucines 2 and 5, which can be retained by a membrane reactor system, have been prepared and used as catalysts for the continuously operated asymmetric epoxidation of chalcone. The optimized batch reaction conditions yield epoxychalcone in high enantioselectivities (up to 94%) and conversions (over 99%) after 15 minutes.
Key words
enantioselective epoxidation - homogeneous catalysis - trans-chalcone epoxides - continuously-operated CMR - oligo(l-leucine)s