Synlett 2002(6): 1008-1010
DOI: 10.1055/s-2002-31914
LETTER
© Georg Thieme Verlag Stuttgart · New York

Cross-coupling between 3-Pyridylmagnesium Chlorides and Heteroaromatic Halides

Véronique Bonneta, Florence Mongin*a, François Trécourta, Gilles Bretona, Francis Marsaisa, Paul Knochelb, Guy Quéguinera
a Laboratoire de Chimie Organique Fine et Hétérocyclique, UMR 6014, IRCOF, Place E. Blondel, BP 08, 76131 Mont-Saint-Aignan cedex, France
b Ludwig-Maximilians-Universität München, Department Chemie, Butenandtstr, 5-13, Haus F, 81377 München, Germany
Fax: +33(2)32522962; e-Mail: florence.mongin@insa-rouen.fr;
Further Information

Publication History

Received 20 March 2002
Publication Date:
07 February 2007 (online)

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Abstract

Phenyl- and thienylpyridines were prepared by Pd(0)-catalyzed cross-coupling of 3-pyridylmagnesium chlorides with iodobenzene or iodothiophene at room temperature. Starting from bromo and chloro azines and diazines, the Ni(0)-catalyzed reaction proved more suitable to allow the synthesis of pyridylpyridines, pyridylquinolines and pyridyldiazines.