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Probes for Narcotic Receptor Mediated Phenomena; 29: Synthesis of rac-(4R,6aR,11bR)-3-Methyl-2,3,4,5,6,6a-hexahydro-1H-4,11b-methanobenzo­furo[3,2-d]azocin-10-ol, the para-a Oxide-Bridged Phenylmorphan Isomer, and a New Route to rac-(4R,6aR,11bR)-3-Methyl- 2,3,4,5,6,6a-hexahydro-1H-4,11b-methanobenzofuro[3,2-d]azocin-8-ol, the ortho-a Oxide-Bridged Phenylmorphan­ Isomer

Koichiro Yamadaa, Judith L. Flippen-Andersonb, Arthur E. Jacobsona, Kenner C. Rice*a
a Laboratory of Medicinal Chemistry, Building 8, Room B1-23, National Institute of Diabetes and Digestive and Kidney Diseases, National­ Institutes of Health, Bethesda, Maryland, 20892-0815, USA
Fax: +1(301)4020589; e-Mail: kr21f@nih.gov;
b Laboratory for the Structure of Matter, Naval Research Laboratory, Washington D.C., 20375, USA