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Synlett 2003(2): 0191-0194
DOI: 10.1055/s-2003-36791
DOI: 10.1055/s-2003-36791
LETTER
© Georg Thieme Verlag Stuttgart · New York
Trichloroisocyanuric Acid/NaNO2 as a Novel Heterogeneous System for the Selective Mononitration of Phenols under Mild Conditions
Further Information
Received
22 September 2002
Publication Date:
22 January 2003 (online)
Publication History
Publication Date:
22 January 2003 (online)
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Abstract
Nitrophenols can be obtained via direct nitration of phenols with trichloroisocyanuric acid, NaNO2 and wet SiO2 at room temperature in moderate to high yields.
Key words
trichloroisocyanuric acid - nitrophenols - sodium nitrite
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References
Dichloromethane is the best solvent for the nitration of phenols due to its low boiling point. We know that 4-nitrophenols are very volatile and should be distilled with high boiling point solvents otherwise the yield of reaction will be decreased (due to intramolecular hydrogen bonding).