Abstract
The terdentate ligand 2,2′:6′,2′′-terpyridine
(tpy) has increasingly become one of the most popular ligands in
coordination chemistry. A variety of substituents are utilised to
tailor the properties of its metal complexes. 2,2′:6′,2′′-Terpyridine
was reacted with almost all transition metals to form complexes.
Among a series of tpy ligand derivatives, those containing substituents
at the C(4′) position are of especial interest. Metal-bonded
tpy ligands with spacers at C(4′) provide a means of directionality,
and thus a means of linear communication, it means that electronic
communication can occur along the coordination axis. In addition,
the insertion of a single substituent at the C(4′)-position
of the tpy ligand results in no enantiomeric derivatives, as the
derivative retains its plane of symmetry. The synthetic strategies
used to prepare tpy ligands are reviewed comprehensively.
-
1 Introduction
-
2 The Configuration of 2,2′:6′,2′′-Terpyridine
-
3 Methods for the Synthesis of tpy Ligands
-
3.1 Condensation Methodology
-
3.2 Pyrolysis of Hydrazonium Salt
-
3.3 Tohda Methodology
-
3.4 Metal-mediated Methodologies
-
3.5 Sauer Methodology
-
4. Synthesis of Ligands
-
4.1 4′-Aromatic Substituted-2,2′:6′,2′′-terpyridines
-
4.2 Synthesis of tpy Ligands Possessing Functional
Groups Directly Attached to C(4′)
-
4.2.1 Preparation of Trimethyl Derivatives of 2,2′:6′,2′′-Terpyridine
-
4.2.2 Carbonyl Derivatives of tpy Ligands
-
4.2.3 Synthesis of 4′-Carbaldehyde Oxime-2,2′:6′,2′′-terpyridine
-
4.2.4 Carboxylate Derivatives of tpy Ligands
-
4.2.5 Synthesis of 4′-Nitro-2,2′:6′,2′′-Terpyridines
-
4.2.6 Synthesis of 4′-Hydroxy-2,2′:6′,2′′-terpyridines
-
4.2.7 Synthesis of 4′,4′-Bis(2,2′:6′,2′′-terpyridyl)amine
-
4.2.8 Synthesis of 4′-Thio-substituted 2,2′:6′,2′′-Terpyridines
-
4.2.9 Synthesis of 2,2′:6′,2′′-Terpyridine-1′-oxides
-
5 Conclusion
Key words
terpyridine - bipyrdine - oligopyridine oxide - coupling reaction - supramolecular chemistry
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