A Novel One-pot Conversion of Aldehydes to (E)-α-Fluoro-β-trifluoromethyl-allylic Alcohols

Yanchang  Shen; Guoping  Wang

doi:10.1055/s-2003-36819

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A Novel One-pot Conversion of Aldehydes to (E)-α-Fluoro-β-trifluoromethyl-allylic Alcohols

Yanchang Shen*, Guoping Wang
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Linglin Lu, Shanghai 200032, China
Fax: +86(21)64166128; e-Mail: shenyc@pub.sioc.ac.cn;

Abstract

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Abstract

A novel one-pot conversion of aldehydes to (E)-α-fluoro-β-trifluoromethyl allylic alcohols by using (Z)-α-fluoro-β-trifluoromethylvinylstannanes as new synthetic reagents is described.

Key words

one-pot conversion - polyfluorinated compounds - allylic alcohols - vinyl stannanes

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References

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