The Addition of Azomethine Ylides to [60]Fullerene Leading to Fulleropyrrolidines

Nikos Tagmatarchis; Maurizio Prato

doi:10.1055/s-2003-38725

ACCOUNT

The Addition of Azomethine Ylides to [60]Fullerene Leading to Fulleropyrrolidines

Nikos Tagmatarchis, Maurizio Prato*
Dipartimento di Scienze Farmaceutiche, Università di Trieste, Piazzale Europa 1, 34127 Trieste, Italy
Fax: +39(40)52572; e-Mail: prato@units.it;

Abstract

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Abstract

This account reports recent developments in the synthesis of fulleropyrrolidines, prepared via 1,3 dipolar cycloaddition of azomethine ylides to fullerenes. The versatility of this approach makes fulleropyrrolidines an attractive target to an interdisciplinary community of researchers. In addition, the fullerene derivatives are more soluble in polar solvents, so that they can self-assemble in complex supramolecular architectures or form novel hybrid systems with potential applications in biological and technological areas.

Key words

fullerenes - cycloadditions - azomethine ylides - pyrrolidines - materials chemistry - biological applications

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