Simple, Economical andEnvironmentally Benign Selective Regeneration of Carbonyl Compoundsfrom Oximes and N,N-DimethylHydrazones

D. Subhas Bose; A. V. Narsimha Reddy; A. P. Rudra Das

doi:10.1055/s-2003-40998

SHORTPAPER

Simple, Economical andEnvironmentally Benign Selective Regeneration of Carbonyl Compoundsfrom Oximes and N,N-DimethylHydrazones

D. Subhas Bose*, A. V. Narsimha Reddy, A. P. Rudra Das
Organic Chemistry Division III, Fine ChemicalLaboratory, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
Fax: +91(40)27160387; e-Mail: dsb@iict.ap.nic.in ;

Abstract

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Abstract

A mild, efficient, selective method for the regeneration of carbonylcompounds from oximes and N,N-dimethylhydrazones in MeCN at ambienttemperature or aqueous media has been carried out in excellent yieldsunder K₅CoW₁₂O₄₀·3 H₂O(0.01 equiv) catalysis.

Key words

hydrazones - catalysis - oximes - aldehydes - ketones - protecting groups

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References

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