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Synthesis 2003(14): 2185-2188
DOI: 10.1055/s-2003-41054
DOI: 10.1055/s-2003-41054
PAPER
© Georg Thieme Verlag Stuttgart · New York
Versatile Transformations of α,β-Dibromoesters and Ketones in Basic Media under Microwave Irradiation
Weitere Informationen
Received
23 June 2003
Publikationsdatum:
28. August 2003 (online)
Publikationsverlauf
Publikationsdatum:
28. August 2003 (online)
Abstract
Depending on the reaction medium, α,β-dibromoesters under microwave irradiation may selectively lead to α-bromoalkenes, to alkenes or to (E)-β-bromostyrenes. The corresponding ketones give selectively the α-bromoketones.
Key words
dehydrobromination - debromination - solvent-free reaction - microwaves
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