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Synthesis 2004(3): 331-333
DOI: 10.1055/s-2004-815934
DOI: 10.1055/s-2004-815934
SHORTPAPER
© Georg Thieme Verlag Stuttgart · New York
Synthesis of Ferrocenylethynyl Ketones by Coupling of Ferrocenylethyne with Acyl Chlorides
Weitere Informationen
Received
9 October 2003
Publikationsdatum:
26. Januar 2004 (online)
Publikationsverlauf
Publikationsdatum:
26. Januar 2004 (online)
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Abstract
Some new ethynyl ketones containing ferrocenyl moieties were prepared conveniently by coupling ferrocenylethyne with acyl chlorides in the presence of a catalytic amount of PdCl2(PPh3)2/PdBzCl(PPh3)2-CuI. This coupling reaction proceeded smoothly in a dry argon atmosphere at room temperature and gave coupling products in satisfactory yields.
Key words
ferrocene - ferrocenylethynyl ketones - Sonogashira coupling - acyl chlorides - Pd-catalysis
- 1
Green MLH.Marder SR.Thomson ME. Nature 1987, 330: 360 - 2
Eaton DF. Science 1991, 253: 281 - 3
König B.Zieg H.Bubenitschek P.Jones PO. Chem. Ber. 1994, 127: 1181 - 4
Saswati G.Marek S.Paras PN.Joseph TJ. J. Phys. Chem. 1990, 94: 2847 - 5
Qian Y.Sun YM.Liu JZ.Wu JY.Li FM. Chin. J. Lasers 1998, A25: 231 - 6
Gooding R.Lillya CP.Chiene CW. J. Chem. Soc., Chem. Commun. 1983, 151 - 7
Nakamura N.Maekawahara H.Hanasaki T.Yamaguchi T. Mol. Cryst. Liq. Cryst. 2000, 352: 559 - 8
Vekama K.Hivagana F.Matsuo N.Koinuma H. Chem. Lett. 1978, 703 - 9
Solcaniora E.Toma S.Fiedlerova A. Org. Magn. Reson. 1980, 181 - 10
Trevor SA.William EW. J. Chem. Soc., Perkin Trans. 1 1977, 1527 - 11
Stepnicka P.Trojan L.Kubista J.Ludvik J. J. Organomet. Chem. 2001, 637-639: 291 - 12
Tohda Y.Sonagashira K.Hagihara N. Synthesis 1977, 777 - 13
Sonagashira K. In Handbook of Organopalladium Chemistry for Organic Synthesis Vol. 1:Negishi E. Wiley; New York: 2002. p.493 - 14
Burton G.Elder JS.Fell SCM.Tachulski SAV. Tetrahedron Lett. 1988, 29: 3003 - 15
Luo SJ.Liu YH.Liu CM.Liang YM.Ma YX. Synth. Commun. 2000, 30: 1755