InBr3-Catalyzed Deoxygenative Allylation of Benzylic and Allylic Alcohols and Acetates with Allyltrimethylsilane

Sang Hee Kim; Chul Shin; Ae Nim Pae; Hun Yeong Koh; Moon Ho Chang; Bong Young Chung; Yong Seo Cho

doi:10.1055/s-2004-829109

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Synthesis 2004(10): 1581-1584
DOI: 10.1055/s-2004-829109

PAPER

InBr₃-Catalyzed Deoxygenative Allylation of Benzylic and Allylic Alcohols and Acetates with Allyltrimethylsilane

Sang Hee Kim^a,b, Chul Shin^a, Ae Nim Pae^a, Hun Yeong Koh^a, Moon Ho Chang^a, Bong Young Chung^b, Yong Seo Cho*^a
^a Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul 130-650, South Korea
Fax: +82(2)9585189; e-Mail: ys4049@kist.re.kr;
^b Department of Chemistry, Korea University, Seoul 136-701, South Korea

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Publication History

Received 17 September 2003
Publication Date:
23 June 2004 (online)

Abstract
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Abstract

Deoxygenative allylations of benzylic and allylic alcohols and acetates with allyltrimethylsilane in the presence of a catalytic amount of InBr₃ (5 mol%) were successfully achieved in high yields.

Key words

benzyl alcohol - allyl acetate - benzyl acetate - deoxygenative allylation - indium halide

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