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Synthesis 2004(13): 2115-2120
DOI: 10.1055/s-2004-829172
DOI: 10.1055/s-2004-829172
PAPER
© Georg Thieme Verlag Stuttgart · New York
Synthesis and Reactions of Paramagnetic Aromatic Aldehydes as Useful Synthetic Building Blocks
Weitere Informationen
Received
6 May 2004
Publikationsdatum:
27. Juli 2004 (online)
Publikationsverlauf
Publikationsdatum:
27. Juli 2004 (online)
![](https://www.thieme-connect.de/media/synthesis/200413/lookinside/thumbnails/10.1055-s-2004-829172-1.jpg)
Abstract
Starting from paramagnetic benzaldehyde, a benzophenone-type photoactivable spin label, paramagnetic warfarin and phenindione were synthesized. Nitration of protected benzylic alcohol led to 2-nitrobenzylmethanethiosulfonate, a thiol specific spin label, and 2-nitroaldehyde, which was a key compound for paramagnetic indigo, salicylic acid and nifedipine.
Key words
anticoagulant - free radicals - drugs - indole - pyridines
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