The Development of A3-Coupling (Aldehyde-Alkyne-Amine) and AA3-Coupling (Asymmetric Aldehyde-Alkyne-Amine)

Chunmei Wei; Zigang Li; Chao-Jun Li

doi:10.1055/s-2004-829531

ACCOUNT

The Development of A³-Coupling (Aldehyde-Alkyne-Amine) and AA³-Coupling (Asymmetric Aldehyde-Alkyne-Amine)

Chunmei Wei^a, Zigang Li^a, Chao-Jun Li*^a,b
^a Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, USA
^b Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal, Quebec H3A 2K6, Canada
Fax: +1(514)3983797; e-Mail: cj.li@mcgill.ca;

Abstract

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Abstract

This account briefly describes the authors’ recent efforts to develop the catalytic coupling of aldehyde, alkyne, and amine, as well the asymmetric catalytic coupling of aldehyde, alkyne, and amine.

1 Introduction

2 Background

3 The Development of Aldehyde-Alkyne-Amine Coupling (A³-Coupling)

3.1 Catalyzed by Cu (I)

3.2 Catalyzed by [Ru-Cu]

3.3 Catalyzed by Ir(I)

3.4 Catalyzed by [Au]

3.5 Catalyzed by Ag(I)

4 The Development of Asymmetric Aldehyde-Alkyne-Amine Coupling (AA³-Coupling)

4.1 Catalyzed by [Cu]

4.2 Catalysis as Reported by Others

5 Conclusion

Key words

aldehyde-alkyne-amine coupling - asymmetric - catalysis

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Referenzen

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