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Synlett 2004(9): 1472-1483
DOI: 10.1055/s-2004-829531
DOI: 10.1055/s-2004-829531
ACCOUNT
© Georg Thieme Verlag Stuttgart · New York
The Development of A3-Coupling (Aldehyde-Alkyne-Amine) and AA3-Coupling (Asymmetric Aldehyde-Alkyne-Amine)
Weitere Informationen
Received
1 February 2004
Publikationsdatum:
29. Juni 2004 (online)
Publikationsverlauf
Publikationsdatum:
29. Juni 2004 (online)
![](https://www.thieme-connect.de/media/synlett/200409/lookinside/thumbnails/10.1055-s-2004-829531-1.jpg)
Abstract
This account briefly describes the authors’ recent efforts to develop the catalytic coupling of aldehyde, alkyne, and amine, as well the asymmetric catalytic coupling of aldehyde, alkyne, and amine.
1 Introduction
2 Background
3 The Development of Aldehyde-Alkyne-Amine Coupling (A3-Coupling)
3.1 Catalyzed by Cu (I)
3.2 Catalyzed by [Ru-Cu]
3.3 Catalyzed by Ir(I)
3.4 Catalyzed by [Au]
3.5 Catalyzed by Ag(I)
4 The Development of Asymmetric Aldehyde-Alkyne-Amine Coupling (AA3-Coupling)
4.1 Catalyzed by [Cu]
4.2 Catalysis as Reported by Others
5 Conclusion
Key words
aldehyde-alkyne-amine coupling - asymmetric - catalysis
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