Abstract
The preparation of a solid Pd(II)-precatalyst and its use in microwave-assisted Suzuki-Miyaura reactions in water is described. The precatalyst is obtained by treatment of 4-pyridine-aldoxime with Na2 PdCl4 and is insoluble in organic solvents as well as in water. Its robustness under microwave conditions and its insolubility allows simple reuse in ‘teabags’.
Key words
Suzuki-Miyaura reactions - precatalyst - pyridine-aldoxime Pd-catalyst
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