TEMPO-Mediated Environmentally Benign Oxidation of Primary Alcohols to Carboxylic Acids with Poly[4-(diacetoxyiodo)styrene]

Yousuke Tashino; Hideo Togo

doi:10.1055/s-2004-830881

LETTER

TEMPO-Mediated Environmentally Benign Oxidation of Primary Alcohols to Carboxylic Acids with Poly[4-(diacetoxyiodo)styrene]

Yousuke Tashino^a, Hideo Togo*^a,b
^a Graduate School of Science and Technology, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263-8522 Japan
^b Department of Chemistry, Faculty of Science, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263-8522 Japan
e-Mail: togo@faculty.chiba-u.jp;

Abstract

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Abstract

An operationally simple and environmentally benign oxidation of primary alcohols to the corresponding carboxylic acids with a TEMPO-mediated poly[4-(diacetoxyiodo)styrene] system in acetone and water was carried out.

Key words

oxidation - alcohol - carboxylic acid - aldehyde - TEMPO - poly[4-(diacetoxyiodo)styrene] - environmentally benign

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Referenzen

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Carboxylic acids were identified by comparison with commercially available authentic materials.