Abstract
This review with 206 references covers the literature published until March 2004 on the development and applications of new efficient catalyst systems for the Suzuki palladium-catalysed cross-coupling reaction of organoboron compounds with organic electrophiles. Where possible, the relative advantages of the new catalyst systems in this synthetically very important carbon-carbon bond forming reaction have been compared.
1 Introduction
2 Palladacycle Complexes as Catalyst Precursors
3 Catalyst Systems Composed of Pd(0) or Pd(II) Derivatives and Electron-Rich and/or Bulky Phosphine Ligands
4 Catalyst Systems Composed of Pd(0) or Pd(II) Derivatives and N -Heterocyclic Carbene Ligands
5 Water-Soluble Catalyst Precursors
6 Ligandless Catalyst Precursors
7 Other Novel Pd Catalyst Precursors
8 Conclusions
Key words
palladium - complexes - boron - catalysis - cross-coupling
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