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Synthesis 2004(18): 2943-2958
DOI: 10.1055/s-2004-834932
DOI: 10.1055/s-2004-834932
REVIEW
© Georg Thieme Verlag Stuttgart · New York
Recent Advances in the Asymmetric Hydrosilylation of Ketones, Imines and Electrophilic Double Bonds
Weitere Informationen
Received
14 July 2004
Publikationsdatum:
24. November 2004 (online)
Publikationsverlauf
Publikationsdatum:
24. November 2004 (online)
Abstract
This literature review focuses on the recent advances in the asymmetric hydrosilylation of ketones and imines. New catalyst systems based on various transition metals, such as rhodium, titanium, zinc, copper and tin, combined with classical or new ligand structures, are presented. These systems lead to very effective and selective protocols for the reduction of prochiral ketones, imines and electrophilic double bonds.
1 Introduction
2 Rhodium-Based Catalysts
3 Titanium-Based Catalysts
3.1 Hydrosilylation of Ketones
3.2 Hydrosilylation of Imines
4 Zinc-Based Catalysts
5 Copper-Based catalysts
5.1 Asymmetric Hydrosilylation of Electrophilic Double Bonds
5.2 Asymmetric Hydrosilylation of Ketones and Imines
6 Conclusions
Key words
asymmetric catalysis - asymmetric hydrosilylation - chiral ligands - rhodium - titanium - zinc - conjugate addition - reduction
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