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Synlett 2005(1): 75-78
DOI: 10.1055/s-2004-837195
DOI: 10.1055/s-2004-837195
LETTER
© Georg Thieme Verlag Stuttgart · New York
New Heteropolyacids as Catalysts for the Selective Oxidation of Sulfides to Sulfoxides with Hydrogen Peroxide
Further Information
Received
16 September 2004
Publication Date:
07 December 2004 (online)
Publication History
Publication Date:
07 December 2004 (online)
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Abstract
Pyridinium salts of Keggin-type molybdovanadophosphates proved to be highly active catalysts for the hydrogen peroxide oxidation of sulfides to the corresponding sulfoxide and sulfone derivatives. High conversion and high selectivity for sulfoxide were observed.
Key words
sulfides - sulfoxides - oxidation - hydrogen peroxide - Keggin-type molybdovanadophosphate pyridinium salts
- 1
Trost BM. Chem. Rev. 1978, 78: 363 - 2
Kar G.Saikia A.Bora U.Dehury S.Chaudhuri M. Tetrahedron Lett. 2003, 44: 4503 - 3
Varma R.Sain R.Meshram H. Tetrahedron Lett. 1997, 38: 6525 ; and references cited therein - 4
Tajbakhsh M.Hosseinzadeh R.Shakoori A. Tetrahedron Lett. 2004, 45: 1889 ; and references cited therein - 5
Barton D.Li W.Smith J. Tetrahedron Lett. 1998, 39: 7055 - 6
Iwahana T.Sakaguchi S.Ishii Y. Tetrahedron Lett. 1998, 39: 9059 - 7
Bonadies F.De Angelis F.Locati L.Scettri A. Tetrahedron Lett. 1996, 37: 7129 - 8
Martin S.Rossi L. Tetrahedron Lett. 2001, 41: 7147 - 9
Suarez A.Rossi L.Martin S. Tetrahedron Lett. 1995, 36: 1201 - 10
Xu W.Li Y.Zhang Q.Zhu H. Synthesis 2004, 227 - 11
Gunaratne H.McKervey M.Feutren S.Finlay J.Boyd J. Tetrahedron Lett. 1998, 39: 5655 - 12
Matteucci M.Bhalay G.Bradley M. Org. Lett. 2003, 5: 235 - 13
Palucki M.Hanson P.Jacobsen E. Tetrahedron Lett. 1992, 33: 7111 - 14
Saito B.Katsuki T. Tetrahedron Lett. 2001, 42: 3873 - 15
Kim KS.Hwang H.Cheong C.Hahn C. Tetrahedron Lett. 1990, 31: 2893 - 16
Oae S.Watanabe Y.Fujimori K. Tetrahedron Lett. 1983, 24: 5903 - 17
Vázquez P.Blanco M.Cáceres C. Catal. Lett. 1999, 60: 205 - 18
Villabrille P.Romanelli G.Vázquez P.Cáceres C. Appl. Catal., A, in press - 19
Davis M.Dillon C.Holles J.Labinger J. Angew. Chem. Int. Ed. 2002, 41: 858