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Synthesis 2005(3): 407-410  
DOI: 10.1055/s-2004-837285
PAPER
© Georg Thieme Verlag Stuttgart · New York

An Easy Transformation of 2-Amino-2-(hydroxyimino)acetates to Carbamoylformamidoximes

Demetrios N. Nicolaides*a, Konstantinos E. Litinasa, Theodora Papamehaela, Hanna Grzeskowiaka, Daman R. Gautama, Konstantina C. Fylaktakidoub
a Laboratory of Organic Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54124, Greece
Fax: +30(231)0997679; e-Mail: nicol@chem.auth.gr; e-Mail: klitinas@chem.auth.gr;
b Molecular Biology and Genetics Department, Democritus University of Thrace, Alexandroupolis 68100, Greece
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Publication History

Received 19 July 2004
Publication Date:
08 December 2004 (online)

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Abstract

Carbamoylformamidoximes 5 are synthesized from 2-amino-2-(hydroxyimino)acetates 3 by reaction with aminomagnesium bromides 4, prepared in situ from amines 2 and ethylmagnesium bromide.

Key words

amides - amines - amidoximes - amidines - organometallic reagents