Synthesis 2005(5): 725-730  
DOI: 10.1055/s-2005-861803
PAPER
© Georg Thieme Verlag Stuttgart · New York

An Efficient and Diastereoselective Synthesis of trans β-Lactams and β-Aminocarbonyl Compounds

Shan-Zhong Jian, Cheng Ma, Yan-Guang Wang*
Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China
Fax: +86(571)87951512; e-Mail: orgwyg@zju.edu.cn;
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Publikationsverlauf

Received 13 September 2004
Publikationsdatum:
09. Februar 2005 (online)

Abstract

Efficient and diastereoselective syntheses of trans β-lactams and anti β-aminocarbonyl compounds from carboximide 1 and imines 2 under the classical Reformatsky reaction conditions are described. An enolate-imine mechanism has been proposed for this reaction.