A Facile β-Cyclodextrin-Catalyzed Oxidative Deprotection of tert-Butyl­dimethylsilyl (TBDMS) Ethers with NBS in Water

M. Somi Reddy; M. Narender; Y. V. D. Nageswar; K. Rama Rao

doi:10.1055/s-2005-861808

SHORTPAPER

A Facile β-Cyclodextrin-Catalyzed Oxidative Deprotection of tert-Butyldimethylsilyl (TBDMS) Ethers with NBS in Water [1]

M. Somi Reddy, M. Narender, Y. V. D. Nageswar, K. Rama Rao*
Organic Chemistry Division I, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Fax: +91(40)27160757; e-Mail: drkrrao@yahoo.com;

Abstract

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Abstract

Treatment of TBDMS ethers with NBS in the presence of β-cyclodextrin in water results, for the first time, in the cleavage of the silicon-oxygen bond, carbonyl compounds are obtained upon oxidation.

Keywords

TBDMS ethers - NBS - carbonyl compounds - β-cyclodextrin - biomimetic - water

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References

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A Facile β-Cyclodextrin-Catalyzed Oxidative Deprotection of tert-Butyl­dimethylsilyl (TBDMS) Ethers with NBS in Water [1]

A Facile β-Cyclodextrin-Catalyzed Oxidative Deprotection of tert-Butyldimethylsilyl (TBDMS) Ethers with NBS in Water [1]