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Synthesis 2005(6): 998-1004
DOI: 10.1055/s-2005-861841
DOI: 10.1055/s-2005-861841
PAPER
© Georg Thieme Verlag Stuttgart · New York
Preparation of para-Terphenylylalkanethiols with Different Chain Lengths
Further Information
Received
20 August 2004
Publication Date:
21 February 2005 (online)
Publication History
Publication Date:
21 February 2005 (online)
Abstract
Terphenylylalkanethiols with different chain length were synthesized using palladium-catalyzed cross-coupling reactions. While the thiols with two and three methylene groups were obtained via photoaddition of thiopivalic acid to the respective alkenes, the longer terphenylylalkanethiols were synthesized by two consecutive Kumada cross-coupling reactions followed by a Mitsunobu reaction for the introduction of the sulfur functionality.
Key words
cross-coupling - Mitsunobu reaction - self-assembly - thiols - arylations
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