Synthesis of Disulfides Containing a Corrinoid Head Group for Preparation of Self-Assembled Monolayers

Abstract

The synthesis of three novel alkane disulfides with headgroups derived from vitamin B₁₂, 14a, 14b and 15, is described. Self-assembled monolayers on gold are prepared from the symmetrical disulfide 15, bearing two cobyrinate head groups. The coating of the gold surface is analyzed by TOF-SIMS and ESCA measurements.

Key words

disulfides - vitamin B₁₂ derivatives - cobester disulfides - self-assembled monolayers

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12

Mikrosysteme - Nanosysteme, Bull. Swiss Fed. Inst. of Techn./Zürich, No. 292, Feb. 2004.

49

Szöcs, E.; Durrer, L.; Luginbühl, R.; Simic, N.; Viana, A.; Abrantes, L.; Keese, R.; Siegenthaler, H., manuscript in preparation.