Synthesis of Unique Ionophores of Penta-Crown Ethers

Zhi Bin Huang; Seung Hyun Chang

doi:10.1055/s-2005-871964

LETTER

Synthesis of Unique Ionophores of Penta-Crown Ethers

Zhi Bin Huang^a,b, Seung Hyun Chang*^a
^a Department of Chemistry, Daegu University, Kyongbuk 712-714, Korea
^b College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China
Fax: +82(53)8506449; e-Mail: shchang@daegu.ac.kr;

Abstract

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Abstract

Structurally unique novel ionophores of penta-crown ethers were successfully synthesized. Diaza-18-crown-6 was designed as the parent crown ring. The penta-crown ethers were prepared by the reaction of 1,3,5-triacryloylhexahydro-1,3,5-triazine (TAHTA) with diaza 18-crown-6 followed by a Michael reaction. The binding interactions of the newly synthesized penta-crown ethers with alkali metal cations were examined; the results indicate that the new penta-crown ethers can bind alkali cations of different sizes.

Key words

diaza-crown ether - 1-aza-crown ether - penta-crown ether - Michael addition - ionophore

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Referenzen

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