Abstract
Reactions of vinylidenecyclopropanes with diaryl diselenide catalyzed by iodosobenzene diacetate produced the corresponding addition products 4 in moderate to good yields under mild conditions. The further transformation of 4 to the corresponding methylenecyclopropanes 5 has been disclosed in the presence of hydrogen peroxide (H2 O2 ) in toluene.
Key words
arylvinylidenecyclopropanes - diaryl diselenide - iodosobenzene diacetate - methylenecyclopropanes - addition reaction
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General Procedure.
2
2
