Synthesis 2005(19): 3346-3354  
DOI: 10.1055/s-2005-918457
PAPER
© Georg Thieme Verlag Stuttgart · New York

Synthesis of Polysubstituted Pyrroles from Nitroso-Diels-Alder Cycloadducts

Géraldine Calvet, Nicolas Blanchard, Cyrille Kouklovsky*
Laboratoire de Synthèse des Substances Naturelles, ICMMO, UMR 8615, Batiment 410, Université d’Orsay, 91400 Orsay, France
Fax: +33(1)69154679; e-Mail: cykouklo@icmo.u-psud.fr;
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Publikationsverlauf

Received 2 May 2005
Publikationsdatum:
04. November 2005 (online)

Abstract

Nitroso-Diels-Alder cycloaddition of various dienes combined with a straightforward sequence including N-O bond cleavage and oxidation reaction of the resulting (Z)-γ-aminoenone (or enal) leads to polysubstituted pyrrolic units.