Highly Efficient Catalysts for Epoxidation Mediated by Iminium Salts

Philip C. Bulman Page; Benjamin R. Buckley; Louise F. Appleby; Paul A. Alsters

doi:10.1055/s-2005-918483

PAPER

Highly Efficient Catalysts for Epoxidation Mediated by Iminium Salts

Philip C. Bulman Page*^a, Benjamin R. Buckley^a, Louise F. Appleby^a, Paul A. Alsters^b
^a Department of Chemistry, Loughborough University, Loughborough, LE11 3TU, UK
Fax: +44(1509)223926; e-Mail: p.c.b.page@lboro.ac.uk;
^b DSM Pharma Chemicals, Advanced Synthesis and Catalysis, P.O. Box 18, 6160 MD Geleen, The Netherlands

Abstract

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Abstract

A range of substituted dihydroisoquinolinium salts has been tested in the catalytic epoxidation of several alkenes. Catalyst loadings as low as 0.5 mol% have been used in the epoxidation of 1-phenylcyclohexene.

Key words

catalysis - epoxidations - oxidations - iminium salt - oxaziridinium salt

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Referenzen

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