Deoxygenation of Sulfoxide and Aza-aromatic N-Oxide Using a Protocol of Indium and Acyl Chloride

Eun Soo Park; Seung Hwan Lee; Ji Hee Lee; Hak June Rhee; Cheol Min Yoon

doi:10.1055/s-2005-918492

SHORTPAPER

Deoxygenation of Sulfoxide and Aza-aromatic N-Oxide Using a Protocol of Indium and Acyl Chloride

Eun Soo Park^a, Seung Hwan Lee^a, Ji Hee Lee^a, Hak June Rhee^b, Cheol Min Yoon*^c
^a Graduate School of Biotechnology, Korea University, Sungbuk-ku Anamdong 5, 1 ga, 136-701 Seoul, South Korea
^b College of Science and Technology, Hanyang University, Sangnok-ku Sa-1 dong 1271, 425-791 Kyeonggi-do, South Korea
^c Department of Advanced Material Chemistry, Korea University, Jochiwon, 339-800 Choongnam, South Korea
Fax: +82(2)32903433; e-Mail: cmyoon@korea.ac.kr;

Abstract

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Abstract

Sulfoxides and aza-aromatic N-oxides were deoxygenated using a system of indium and pivaloyl chloride at room temperature to give the corresponding sulfides and aza-aromatics in high yields.

Key words

deoxygenation - sulfoxide - aza-aromatic N-oxides - indium - sulfide

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Referenzen

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