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Synthesis 2006(2): 224-226
DOI: 10.1055/s-2005-918507
DOI: 10.1055/s-2005-918507
SHORTPAPER
© Georg Thieme Verlag Stuttgart · New York
Phosphorus Pentasulfide: A Mild and Versatile Reagent for the Preparation of Thioamides from Nitriles
Weitere Informationen
Publikationsverlauf
Received
19 July 2005
Publikationsdatum:
21. Dezember 2005 (online)


Abstract
A simple, efficient, and new method has been developed for the synthesis of thioamides from nitriles. The reaction of a variety of aromatic and aliphatic nitriles in the presence of phosphorus pentasulfide afforded the corresponding thioamides in high yields. This method is easy, rapid, and high-yielding for the synthesis of thioamides from nitriles.
Key words
thioamides - nitriles - phosphorus pentasulfide - phosphorodithioates - addition reactions