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Synthesis 2006(15): 2608-2612
DOI: 10.1055/s-2006-942443
DOI: 10.1055/s-2006-942443
PAPER
© Georg Thieme Verlag Stuttgart · New York
Er(OTf)3 as a Valuable Catalyst in a Short Synthesis of 2′,3′-Dideoxy Pyranosyl Nucleosides via Ferrier Rearrangement
Weitere Informationen
Received
14 February 2006
Publikationsdatum:
28. Juni 2006 (online)
Publikationsverlauf
Publikationsdatum:
28. Juni 2006 (online)
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Abstract
Er(OTf)3 is a useful catalyst for the Ferrier rearrangement furnishing 2′,3′-dideoxy pyranosyl nucleosides easily by means of cleaner reaction profiles, short reaction times, mild reaction conditions, good stereoselectivity, and good recoverability of the commercially available catalyst.
Key words
Ferrier rearrangement - erbium(III) triflate - Lewis acid catalyst - nucleosides - glycals
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References
The purity of recovered Er(OTf)3 was confirmed by comparison with the IR spectrum of the commercial product.