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Synlett 2006(10): 1569-1573
DOI: 10.1055/s-2006-944187
DOI: 10.1055/s-2006-944187
LETTER
© Georg Thieme Verlag Stuttgart · New York
Kinetic Resolution in Vanadium-Catalyzed Sulfur Oxidation as an Efficient Route to Enantiopure Aryl Benzyl Sulfoxides
Further Information
Received
28 December 2005
Publication Date:
12 June 2006 (online)
Publication History
Publication Date:
12 June 2006 (online)
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Abstract
Enantiopure aryl benzyl sulfoxides can be prepared using vanadium-Schiff base catalyzed sulfide oxidation and kinetic resolution of the resulting sulfoxide. The kinetic resolution can be effected in combination with asymmetric sulfide oxidation or instead starting from the racemic sulfoxide.
Key words
asymmetric catalysis - oxidation - kinetic resolution - sulfoxides - Schiff bases
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References and Notes
We are very grateful for the assistance and advice received from Carsten Bolm in this area. Ligand 2 was first reported by Anson, see ref. 7f.