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DOI: 10.1055/s-2006-950195
Palladium-Catalyzed Hydroxycarbonylation of Aryl and Vinyl Bromides by Mixed Acetic Formic Anhydride
Publication History
Publication Date:
15 August 2006 (online)
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Abstract
The palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides in the presence of acetic anhydride and lithium formate as a carbon monoxide source has been developed. The combination of palladium(II) acetate with 1,1′-bis(diphenylphosphino)ferrocene (dppf) is an efficient catalytic system when the reaction is carried out at 120 °C.
Key words
hydroxycarbonylation - palladium - catalysis - aryl bromides - carboxylic acids
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References
New address: A. Bessmertnykh, LIMSAG, Université de Bourgogne, UFR Science et Techniques, 9 av. A. Savary, BP 47870, Dijon 21078, France.
2New address: J.-C. Caille, PPG-Sipsy, Z. I. La Croix Cadeau, B. P. 10079, Avrille 49242, France.
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