Catalytic Asymmetric Synthesis of Cyclic α-Allylated α-Fluoroketones

E. C. Burger; B. R. Barron; J. A. Tunge

doi:10.1055/s-2006-950265

LETTER

Catalytic Asymmetric Synthesis of Cyclic α-Allylated α-Fluoroketones

E. C. Burger, B. R. Barron, J. A. Tunge*
Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS 66045-7582, USA
Fax: +1(785)8645396; e-Mail: tunge@ku.edu;

Abstract

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Abstract

This manuscript details the development of an asymmetric, palladium-catalyzed, decarboxylative coupling of fluoroenolates with allyl electrophiles.

Key words

fluorine - enolate - decarboxylation - palladium

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