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Planta Med 1996; 62(5): 465-468
DOI: 10.1055/s-2006-957941
Paper

© Georg Thieme Verlag Stuttgart · New York

New Furostanol Glycosides, Chinenoside IV and V, from Allium chinense

Junpeng Peng1 , Xinsheng Yao2 , Yasuhiro Tezuka3 , Tohro Kikuchi3 , Takao Narui4
  • 1Department of Applied Medicine, Institute Radiation Medicine, 27 Tai-ping Road, Beijing, 100850, China
  • 2Department of Phytochemistry, Shenyang Pharmaceutical University, 103 Wen-hua Road, Shenyang, 110015, China
  • 3Research Institute for Wakan-Yaku (Traditional Sino-Japanese Medicines), Toyama Medical and Pharmaceutical University, Sugitani 2630, Toyama, 930-01, Japan
  • 4Department of Phytochemistry and Pharmacognosy, Meiji College of Pharmacy, Tokyo, 154, Japan
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Publication History

1996

1996

Publication Date:
04 January 2007 (online)

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Abstract

Further studies on water-soluble components in the bulbs of Allium chinense G. Don have led to the isolation of two new furostanol saponins, chinenoside IV(1)and V(2). On the basis of chemical evidence and spectral analyses [1H-, 13C-IMMR (DEPT),1H-1H COSY (COSY45 and p-type), 1H-1H relay-COSY, 1H-13C COSY, HMBC, and FAB-MS], the structure of 1 was established as 26-O- β-glucopyranosyl-3β,26-dihydroxy-23-hydroxymethyl-25(R)-5α-furost-20(22)-en-6-one 3-O-β-xylopyranosyl(1→4)-[α-arabinopyranosyl(1→6)]-β-glucopyranoside and that of 2 to be 26-O-β-glucopyranosyl-3β,26-dihydroxy-23-hydroxymethyl-25-(R)-5α-furost-20(22)-en-6-one 3-O-α-arabinopyranosyl (1→6)-β-glucopyranoside, respectively.

Key words

Allium chinense - G. Don - Liliaceae - furostanol glycoside - chinenoside IV - chinenoside V