A Simple and Efficient Total Synthesis of a Styryllactone, 7-epi-Goniodiol

Gowravaram Sabitha; K. Sudhakar; J. S. Yadav

doi:10.1055/s-2007-965879

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Synthesis 2007(3): 385-388
DOI: 10.1055/s-2007-965879

PAPER

A Simple and Efficient Total Synthesis of a Styryllactone, 7-epi-Goniodiol [1]

Gowravaram Sabitha*, K. Sudhakar, J. S. Yadav
Organic Division I, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Fax: +91(40)27160512; e-Mail: sabitha@iictnet.org;

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Publication History

Received 11 October 2006
Publication Date:
12 January 2007 (online)

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Abstract

Regioselective mono-dihydroxylation, Red-Al reduction, and cis-Horner-Wadsworth-Emmons reactions have been efficiently performed as key steps in the synthesis of 7-epi-goniodiol, isolated from Goniothalamus leiocarpus.

Key words

styryllactones - 7-epi-goniodiol - natural product - asymmetric dihydroxylation - Horner-Wadsworth-Emmons reaction

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IICT Communication No: 060820.