Abstract
A general and efficient method for the synthesis of different poly(β-hydroxyiminoalkyl)amines from aliphatic nitro compounds and amines via terminal N ,N -bis(siloxy)enamine intermediates is described.
Key words
aliphatic nitro compounds - poly(β-hydroxyiminoalkyl)amines -
N ,N -bis(siloxy)enamines - tripod ligands
References
1a
Edison SE.
Hotz RP.
Baldwin MJ.
Chem. Commun. (Cambridge)
2004,
1212
1b
Goldcamp MJ.
Robison SE.
Krause Bauer JA.
Baldwin MJ.
Inorg. Chem.
2002,
41:
2307
2a
Matthaiopoulos G.
Ber. Dtsch. Chem. Ges.
1898,
31:
2396
2b
Korten H.
Scholl R.
Ber. Dtsch. Chem. Ges.
1901,
34:
1904
2c
Ogloblin KA.
Potekhin AA.
J. Org. Chem. USSR (Engl. Transl.)
1965,
399
3
Goldcamp MJ.
Rosa DT.
Landers NA.
Mandel SM.
Krause Bauer JA.
Baldwin MJ.
Synthesis
2000,
2033
4a
Dilman AD.
Tishkov AA.
Lyapkalo IM.
Ioffe SL.
Strelenko YuA.
Tartakosky VA.
Synthesis
1998,
181
4b
Dilman AD.
Tishkov AA.
Lyapkalo IM.
Ioffe SL.
Kachala VV.
Strelenko YuA.
Tartakosky VA.
J. Chem. Soc., Perkin Trans. 1
2000,
2926
4c
Sukhorukov AYu.
Bliznets IV.
Lesiv AV.
Khomutova YuA.
Strelenko YuA.
Ioffe SL.
Synthesis
2005,
1077
5a
Makarenkova LM.
Bliznets IV.
Ioffe SL.
Strelenko YuA.
Tartakovsky VA.
Russ. Chem. Bull.
2000,
49:
1261
5b
Feger H.
Simchen G.
Liebigs Ann. Chem.
1986,
1456
6
Lesiv AV.
Ioffe SL.
Strelenko YuA.
Tartakovsky VA.
Helv. Chim. Acta
2002,
85:
3489
7
Lesiv AV.
Ioffe SL.
Strelenko YuA.
Tartakovsky VA.
Bliznets IV.
Tartakovsky VA.
Mendeleev Commun.
2002,
99
8 An analogue of B , where both chlorine atoms are replaced with NO3 groups, is described.1b
8
9a
Goldcamp MJ.
Krause Bauer JA.
Baldwin MJ.
J. Chem. Crystallogr.
2005,
35:
77
9b
Rosa DT.
Krause Bauer JA.
Baldwin MJ.
Inorg. Chem.
2001,
40:
1606
9c
Goldcamp MJ.
Edison SE.
Squires LN.
Rosa DT.
Vowels NK.
Coker NL.
Krause Bauer JA.
Baldwin MJ.
Inorg. Chem.
2003,
42:
717
10 CCDC 641328 and 641329 contain the supplementary crystallographic data for 6 and 7 , respectively. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk, by e-mailing or faxing a request to deposit@ccdc.cam.ac.uk or +44(1223)336033, respectively, or by writing to the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK.
11 For clathrochelates based on oxime ligands, see: Voloshin YZ.
Varzatskii OA.
Kron TE.
Belsky VK.
Zavodnik VE.
Strizhakova NG.
Palchik AV.
Inorg. Chem.
2000,
39:
1907 ; and references cited therein