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Synthesis 2007(18): 2862-2866  
DOI: 10.1055/s-2007-983847
PAPER
© Georg Thieme Verlag Stuttgart · New York

A Convenient Method for the Synthesis of Poly(β-hydroxyiminoalkyl)amines from Aliphatic Nitro Compounds

Artem N. Semakin, Alexey Yu. Sukhorukov, Alexey V. Lesiv, Yulia A. Khomutova, Sema L. Ioffe*, Konstantin A. Lyssenko
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 119991 Moscow, Russian Federation
Fax: +7(495)1355328; e-Mail: iof@ioc.ac.ru;
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Publikationsverlauf

Received 2 April 2007
Publikationsdatum:
08. August 2007 (online)

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Abstract

A general and efficient method for the synthesis of different poly(β-hydroxyiminoalkyl)amines from aliphatic nitro compounds and amines via terminal N,N-bis(siloxy)enamine intermediates is described.

Key words

aliphatic nitro compounds - poly(β-hydroxyimino­alkyl)amines - N,N-bis(siloxy)enamines - tripod ligands

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CCDC 641328 and 641329 contain the supplementary crystallographic data for 6 and 7, respectively. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk, by e-mailing or faxing a request to deposit@ccdc.cam.ac.uk or +44(1223)336033, respectively, or by writing to the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK.