Palladium-Catalyzed Cascade Reactions of Highly Activated Olefins

Nitin T. Patil; Yoshinori Yamamoto

doi:10.1055/s-2007-984892

ACCOUNT

Palladium-Catalyzed Cascade Reactions of Highly Activated Olefins

Nitin T. Patil, Yoshinori Yamamoto*
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
e-Mail: yoshi@mail.tains.tohoku.ac.jp;

Abstract

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Abstract

In this account, we describe the use of highly activated olefins for palladium-catalyzed reactions. Particularly noteworthy is the creation of new processes using such activated olefins and the efficiency of those processes in building carbon-carbon and carbon-heteroatom bonds under relatively mild conditions. This account is aimed at creating awareness among organic chemists about the use of highly activated olefins in catalytic reactions.

1 Introduction
2 Bisfunctionalization of Highly Activated Olefins
2.1 Alkoxyallylation
2.2 Aminoallylation
2.3 Cyanoallylation
2.4 Bis-allylation
2.5 Propargylallylation
2.6 Acetonation-Allylation
2.7 Alkylallylation
2.8 Hydroallylation
2.9 Synthesis of Dienes/Cope Rearrangement
3 Conclusion

Keywords

palladium - catalysis - decarboxylations - activated olefins - allylations

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