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Synthesis 2007(23): 3627-3634
DOI: 10.1055/s-2007-990824
DOI: 10.1055/s-2007-990824
PAPER
© Georg Thieme Verlag Stuttgart · New York
Stereoselective Total Synthesis of (-)-Aspinolide B from (R)-2,3-O-Isopropylideneglyceraldehyde
Further Information
Received
24 July 2007
Publication Date:
10 October 2007 (online)
Publication History
Publication Date:
10 October 2007 (online)
Abstract
A stereoselective total synthesis of (-)-aspinolide B by a convergent strategy is reported.
Key words
(R)-2,3-O-isopropylideneglyceraldehyde - Jacobsen hydrolytic kinetic resolution - Sharpless asymmetric epoxidation - 1,2-anti selective reduction - Yamaguchi lactonization
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