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DOI: 10.1055/s-2007-990867
Straightforward Synthesis of Novel Biphenyl-Based Macrobicyclic Azathioethers
Publikationsverlauf
Publikationsdatum:
31. Oktober 2007 (online)
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Abstract
The synthesis and characterization of two new macrobicyclic azathioether ligands are reported. The biphenyl-based compounds were prepared by traditional organic reactions and cyclization methods. The identity of one compound was confirmed by X-ray crystallography.
Key words
macrocycles - sulfur - nitrogen - biphenyl
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References
Preliminary analytical data for 5: Mp 76 °C. 1H NMR (400 MHz, CDCl3): δ = 1.36 (s, 9 H, CH3), 2.39 (s, 3 H, CH3), 2.72 (s, 3 H, CH3), 7.07 (s, 1 H, ArH), 7.27 (d, J = 8.0 Hz, 2 H, ArH), 7.42 (d, J = 8.0 Hz, 2 H, ArH).
31CCDC 648984 contains the supplementary crystallographic data for compound L
³
. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html or from the Cambridge Crystallgraphic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(1223)336033;
E-mail: deposit@ccdc.cam.ac.uk.