Direct Synthesis of Functionalized
Allylic Boronic Esters from Allylic Alcohols and Inexpensive Reagents
and Catalysts

Guillaume Dutheuil; Nicklas Selander; Kálmán J. Szabó; Varinder K. Aggarwal

doi:10.1055/s-2008-1067144

PAPER

Direct Synthesis of Functionalized Allylic Boronic Esters from Allylic Alcohols and Inexpensive Reagents and Catalysts

Guillaume Dutheuil^a, Nicklas Selander^b, Kálmán J. Szabó*^b, Varinder K. Aggarwal*^a
^a School of Chemistry, University of Bristol, Cantock’s Close, Bristol, BS8 1TS, UK
Fax: +44(117)9298611; e-Mail: v.aggarwal@bristol.ac.uk;
^b Department of Organic Chemistry, Stockholm University, 106 91 Stockholm, Sweden
e-Mail: kalman@organ.su.se;

Abstract

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Abstract

A remarkably simple and effective system for the direct conversion of allylic alcohols into high value allylic boronic esters using commercially available reagents and catalysts is described.

Key words

allylation - palladium - palladacycles - transition metal

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Referenzen

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