Synthesis of a New Type of d-Mannosamine Glycosyl Donor and Acceptor and their Use for the Preparation of Oligosaccharides Consisting of d-Mannosamine Units Linked by α(1→4)-Glycosidic Bonds

Abstract

Herein, we present the synthesis of three new 2-azido-2-deoxy-d-mannopyranose building blocks that are useful in the preparation of oligosaccharides consisting of α(1→4)-linked 2-azido-2-deoxy-d-mannopyranose units. The successful utilization of these intermediates in the stepwise synthesis of the corresponding trisaccharide is also described in detail.

carbohydrates - glycosylation - oligosaccharides - d-mannosamine

References

<A NAME="RT01808SS-1">1</A>

Present address: Center for Sustainable and Green Chemistry, Department of Chemistry, Building 201, Technical University of Denmark, 2800 Kgs. Lyngby, Denmark.

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