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Synlett 2008(15): 2253-2256  
DOI: 10.1055/s-2008-1078014
LETTER
© Georg Thieme Verlag Stuttgart ˙ New York

Probing the Amino-End Reactivity of Sulfonimidamides

Stéphane Azzaro, Louis Fensterbank*, Emmanuel Lacôte*, Max Malacria*
Laboratoire de Chimie Organique (UMR CNRS 7611), Institut de Chimie Moléculaire (FR 2769), Université Pierre et Marie Curie-Paris 6, C. 229, 4 Place Jussieu, 75005 Paris, France
Fax: +33(1)44277360; e-Mail: louis.fensterbank@upmc.fr; e-Mail: emmanuel.lacote@upmc.fr; e-Mail: max.malacria@upmc.fr.;
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Publication History

Received 15 May 2008
Publication Date:
31 July 2008 (online)

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Abstract

The amino terminus of sulfonimidamides was functionalized through a Mitsunobu reaction. The new sulfonimidamides were engaged in oxidative reactions to provide N-heterocycles.

Key words

aminations - diastereoselectivity - iodine - Mitsunobu reaction - sulfur

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